When heat travels from one solid object to another, not all of the heat is transferred; a lot of it is reflected back at the interface. Our current understanding of how heat propagates across these interfaces is based on the thought that the more ordered the atoms of each object, the more efficient heat transfer will be across the interface. But it turns out our current understanding is dead wrong.
In a recent article published by researchers at the University of Virginia, making the interface rougher, with more defects, was shown to significantly improve the heat transfer across the interface. This was a counter-intuitive result based on the generally accepted understanding of nanoscale heat transfer, and may lead to a fundamental shift in our understanding of how heat is transferred from one object to another.
So how can this be explained? To answer that question we need a basic understanding of how heat is transferred at the atomic scale.
In a solid material, atoms are generally considered to be more or less fixed in place, being held there by bonds with their neighboring atoms. Thermal energy causes the atoms to vibrate - think ball and slinky. If we have a bunch of balls and slinkies at ordered, periodic distances, any vibration in one should be felt further away than if they were randomly oriented, interfering with each other's slinkitude (yes, I just made up that word. Patented.)
But what the researchers showed in this paper is that if you take two separate arrays of balls and slinkies (two different solid materials), and create more of a jumbled up mess at point where one would interact with the other, the vibrations coming from one would more effectively transfer their energy to the other, due to added vibrational modes.
Awesome! This means that if we can fully explain this phenomena, we can learn how to tune thermal properties from being very bad at conducting heat (which would be great for insulation, and for waste heat recovery as a couple examples) to very good at it (which would make computer manufacturers very happy)!